Dear Users, Please have a look at the attached file which contains a table describing the contributions/transitions from first four states only for both the absorption and emission calculations. For absorption, I understand that the final state can be any of the excited states which has highest osc. strength. Am I right? But my doubt is regarding kasha's rule... If you see the emission data, the first excited state has a very low oscillator strength of 0.004 (HOMO-->LUMO(97‰ at 2678.9 nm. However the higher states have a better contribution than this state. So please tell me how to analyse this properly. To my knowledge emission wavelength is around 600-730nm. I would be grateful for any help.
Kind Regards,
This message contains the 31 kb attachment
[ Data.doc ]
Tue Sep 23 '14 12:21pm
This message read 796 times
![[ Previous ]](/ceilidh-icons/ceil_prv.gif){kind=icon}
![[ Next ]](/ceilidh-icons/ceil_nxt.gif){kind=icon}
![[ Index ]](/ceilidh-icons/ceil_ind.gif){kind=icon}
Tue Sep 23 '14 12:21pm![[ Reply ]](/ceilidh-icons/ceil_rep.gif){kind=icon}
![[ Edit ]](/ceilidh-icons/ceil_edt.gif){kind=icon}
![[ Delete ]](/ceilidh-icons/ceil_del.gif){kind=icon}
This message read 796 times