Firefly and PC GAMESS-related discussion club


 
Learn how to ask questions correctly  
 
 
We are NATO-free zone
 



Re^7: Are there any Specific basis sets for ions?

sanya
sanya@photonics.ru


Dear Siddheshwar,

It looks like I see what the problem is. You probably don't quite understand that in quantum chemistry you cannot fix charge on any atom (unlike molecular mechanics). When you remove (or add) an electron from one atom of the entire system, the electron density redistributes in a uniform way. So, you may speak only about overall charge of the system. You may further decompose the resulting electron density into atomic contributions using some procedure (say, Mulliken, Lowdin, NBO, or Bader), but these will be partial charges. Imagine communicating vessels: you cannot take some water from one of them while leaving the water level in the other one intact; the levels immediately become even. Think of electron density as some sort of liquid in a vessel made of nuclear potential.


[ Previous ] [ Next ] [ Index ]           Sat Dec 8 '12 2:29am
[ Reply ] [ Edit ] [ Delete ]           This message read 624 times